Tetrabutylammonium hydroxide 40% in methanol

Product name : Tetrabutylammonium hydroxide 40% in methanol Type of product : Pure substances Product group : Trade product 1.2. Relevant identified u...

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Tetrabutylammonium hydroxide 40% in methanol Safety Data Sheet according to Regulation (EU) 2015/830 Date of issue: 12/09/2018 Doc No: SDS-972.06P/0

SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1.

Product identifier

Product form

: Mixture

Product name

: Tetrabutylammonium hydroxide 40% in methanol

Type of product

: Pure substances

Product group

: Trade product

1.2.

Relevant identified uses of the substance or mixture and uses advised against

1.2.1.

Relevant identified uses

Use of the substance/mixture 1.2.2.

: Laboratory chemicals

Uses advised against

No additional information available. 1.3.

Details of the supplier of the safety data sheet

ISOLAB GmbH Bahnhofstrasse 10, D-97877 Wertheim - Germany T +49 93 42 912 355 - F +49 93 42 912 357 [email protected] 1.4.

Emergency telephone number

Country Germany

Organisation/Company Giftnotruf der Charité

Address

Emergency number +49 30 19240

Hindenburgdamm 30 12203 Berlin

CBF, Haus VIII (Wirtschaftgebäude), UG

Comment

SECTION 2: Hazards identification 2.1.

Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP] Flam. Liq. 2

H225

Acute Tox. 3 (Oral)

H301

Acute Tox. 3 (Dermal)

H311

Acute Tox. 3 (Inhalation:vapour)

H331

Skin Corr. 1

H314

Eye Dam. 1

H318

STOT SE 1

H370

Full text of hazard classes and H-statements : see section 16

Adverse physicochemical, human health and environmental effects Highly flammable liquid and vapour. Causes damage to organs. Toxic in contact with skin. Toxic if inhaled. Toxic if swallowed. Causes serious eye damage. 2.2.

Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display Hazard pictograms (CLP)

:

Signal word (CLP)

: Danger

Hazardous ingredients

: Tetrabutylammonium hydroxide; methanol

Hazard statements (CLP)

: H225 - Highly flammable liquid and vapour. H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H314 - Causes severe skin burns and eye damage. H370 - Causes damage to organs.

Precautionary statements (CLP)

: P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

GHS02

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GHS05

GHS06

GHS08

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Tetrabutylammonium hydroxide 40% in methanol Safety Data Sheet according to Regulation (EU) 2015/830 Date of issue: 12/09/2018 Doc No: SDS-972.06P/0

P280 - Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor. P305+P351+P338+P310 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor. P308+P311 - IF exposed or concerned: Call a POISON CENTER or doctor. P303+P361+P353+P310 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.. Immediately call a POISON CENTER or doctor.

2.3.

Other hazards

No additional information available.

SECTION 3: Composition/information on ingredients 3.1.

Substances

Not applicable 3.2.

Mixtures

Name

Product identifier

Conc. (% w/w)

Classification according to Regulation (EC) No. 1272/2008 [CLP]

methanol

(CAS-No.) 67-56-1 (EC-No.) 200-659-6 (EC Index-No.) 603-001-00-X

59 - 60

Flam. Liq. 2, H225 Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation), H331 STOT SE 1, H370

Tetrabutylammonium hydroxide

(CAS-No.) 2052-49-5 (EC-No.) 218-147-6

40 - 41

Acute Tox. 4 (Oral), H302 Skin Corr. 1, H314 Eye Dam. 1, H318

Product identifier

Specific concentration limits

(CAS-No.) 67-56-1 (EC-No.) 200-659-6 (EC Index-No.) 603-001-00-X

( 3 == 10) STOT SE 1, H370

Specific concentration limits: Name methanol

Full text of H-statements: see section 16

SECTION 4: First aid measures 4.1.

Description of first aid measures

First-aid measures general

: Call a physician immediately.

First-aid measures after inhalation

: Remove person to fresh air and keep comfortable for breathing. Call a doctor.

First-aid measures after skin contact

: Rinse skin with water/shower. Take off immediately all contaminated clothing.

First-aid measures after eye contact

: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician immediately.

First-aid measures after ingestion

: Rinse mouth. Call a physician immediately.

4.2.

Most important symptoms and effects, both acute and delayed

Symptoms/effects after eye contact 4.3.

: Serious damage to eyes.

Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5: Firefighting measures 5.1.

Extinguishing media

Suitable extinguishing media 5.2.

: Water spray. Dry powder. Foam. Carbon dioxide.

Special hazards arising from the substance or mixture

Fire hazard

: Highly flammable liquid and vapour.

Hazardous decomposition products in case of fire

: Toxic fumes may be released.

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5.3.

Advice for firefighters

Protection during firefighting

: Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.

SECTION 6: Accidental release measures 6.1.

Personal precautions, protective equipment and emergency procedures

6.1.1.

For non-emergency personnel

Emergency procedures 6.1.2.

: Ventilate spillage area. NO open flames, NO sparks, and NO smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contact with skin, eyes and clothing.

For emergency responders

Protective equipment 6.2.

: Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection".

Environmental precautions

Avoid release to the environment. 6.3.

Methods and material for containment and cleaning up

Methods for cleaning up

: Take up liquid spill into absorbent material. Notify authorities if product enters sewers or public waters.

Other information

: Dispose of materials or solid residues at an authorized site.

6.4.

Reference to other sections

For further information refer to section 13.

SECTION 7: Handling and storage 7.1.

Precautions for safe handling

Precautions for safe handling

: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Flammable vapours may accumulate in the container. Use explosion-proof equipment. Wear personal protective equipment. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Use only outdoors or in a well-ventilated area.

Hygiene measures

: Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product.

7.2.

Conditions for safe storage, including any incompatibilities

Technical measures

: Ground/bond container and receiving equipment.

Storage conditions

: Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up.

7.3.

Specific end use(s)

No additional information available.

SECTION 8: Exposure controls/personal protection 8.1.

Control parameters

methanol (67-56-1) EU EU EU EU EU Turkey Turkey Turkey Turkey Turkey

8.2.

Local name IOELV TWA (mg/m³) IOELV TWA (ppm) Notes Regulatory reference Local name OEL TWA (mg/m³) OEL TWA (ppm) Comments Regulatory reference

Methanol 260 mg/m³ 200 ppm skin COMMISSION DIRECTIVE 2006/15/EC Metanol 260 mg/m³ 200 ppm Deri 12 Ağustos 2013 Tarihli ve 28733 Sayılı Resmî Gazete

Exposure controls

Appropriate engineering controls: Ensure good ventilation of the work station. 20/09/2018 www.isolab.de

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Tetrabutylammonium hydroxide 40% in methanol Safety Data Sheet according to Regulation (EU) 2015/830 Date of issue: 12/09/2018 Doc No: SDS-972.06P/0

Hand protection: Protective gloves Eye protection: Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: [In case of inadequate ventilation] wear respiratory protection. Environmental exposure controls: Avoid release to the environment.

SECTION 9: Physical and chemical properties 9.1.

Information on basic physical and chemical properties

Physical state

: Liquid

Appearance

: Liquid.

Colour

: colourless to slight yellow

Odour

: No data available on odour.

Odour threshold

: No data available.

pH

: No data available.

Relative evaporation rate (butylacetate=1)

: No data available.

Melting point

: Not applicable

Freezing point

: No data available.

Boiling point

: No data available.

Flash point

: No data available.

Auto-ignition temperature

: No data available.

Decomposition temperature

: No data available.

Flammability (solid, gas)

: Not applicable

Vapour pressure

: No data available.

Relative vapour density at 20 °C

: No data available.

Relative density

: No data available.

Solubility

: No data available.

Log Pow

: No data available.

Viscosity, kinematic

: No data available.

Viscosity, dynamic

: No data available.

Explosive properties

: No data available.

Oxidising properties

: No data available.

Explosive limits

: No data available.

9.2.

Other information

No additional information available.

SECTION 10: Stability and reactivity 10.1.

Reactivity

Highly flammable liquid and vapour. 10.2.

Chemical stability

Stable under normal conditions. 10.3.

Possibility of hazardous reactions

No dangerous reactions known under normal conditions of use. 10.4.

Conditions to avoid

Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition. 20/09/2018 www.isolab.de

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10.5.

Incompatible materials

No additional information available. 10.6.

Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

SECTION 11: Toxicological information 11.1.

Information on toxicological effects

Acute toxicity (oral)

: Oral: Toxic if swallowed.

Acute toxicity (dermal)

: Dermal: Toxic in contact with skin.

Acute toxicity (inhalation)

: Inhalation:vapour: Toxic if inhaled.

ATE CLP (oral) ATE CLP (dermal) ATE CLP (vapours)

147.059 mg/kg bodyweight 500 mg/kg bodyweight 5 mg/l/4h

methanol (67-56-1) LD50 oral rat LD50 dermal rabbit

1187 - 2769 mg/kg (Bibliographic results) < 17100 mg/kg

Skin corrosion/irritation

: Causes severe skin burns and eye damage.

Serious eye damage/irritation

: Causes serious eye damage.

Respiratory or skin sensitisation

: Not classified

Germ cell mutagenicity

: Not classified

Carcinogenicity

: Not classified

Reproductive toxicity

: Not classified

STOT-single exposure

: Causes damage to organs.

STOT-repeated exposure

: Not classified

Aspiration hazard

: Not classified

SECTION 12: Ecological information 12.1.

Toxicity

Ecology - general

: The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment.

Acute aquatic toxicity

: Not classified

Chronic aquatic toxicity

: Not classified

methanol (67-56-1) LC50 fish 1 EC50 Daphnia 1 ErC50 (algae) NOEC (chronic) 12.2.

Persistence and degradability

methanol (67-56-1) Persistence and degradability Biodegradation 12.3.

Readily biodegradable. 95 % 20 d

Bioaccumulative potential

methanol (67-56-1) BCF fish 1 Log Pow Bioaccumulative potential 12.4.

15400 mg/l (Lepomis macrochirus) > 10000 mg/l (Daphnia magna) ≈ 22000 mg/l (Pseudokirchneriella subcapitata) 7900 mg/l (Oryzias latipes)

< 10 (Cyprinus carpio) -0.77 Low bioaccumulation potential.

Mobility in soil

methanol (67-56-1) Ecology - soil 20/09/2018 www.isolab.de

Highly mobile in soil. EN (English)

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12.5.

Results of PBT and vPvB assessment

No additional information available. 12.6.

Other adverse effects

No additional information available.

SECTION 13: Disposal considerations 13.1.

Waste treatment methods

Regional legislation (waste)

: Disposal must be done according to official regulations.

Waste treatment methods

: Dispose of contents/container in accordance with licensed collector’s sorting instructions.

Sewage disposal recommendations

: Disposal must be done according to official regulations.

Additional information

: Flammable vapours may accumulate in the container.

SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN

ADR 14.1. 3286

IMDG

IATA

ADN

RID

3286

UN number 3286

3286

3286

14.2. UN proper shipping name FLAMMABLE LIQUID, FLAMMABLE LIQUID, TOXIC, CORROSIVE, TOXIC, CORROSIVE, N.O.S. (CONTAINS N.O.S. (CONTAINS methanol ; methanol ; Tetrabutylammonium Tetrabutylammonium hydroxide) hydroxide)

Flammable liquid, toxic, corrosive, n.o.s. (CONTAINS methanol ; Tetrabutylammonium hydroxide)

FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. (CONTAINS methanol ; Tetrabutylammonium hydroxide)

FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. (CONTAINS methanol ; Tetrabutylammonium hydroxide)

Transport document description UN 3286 FLAMMABLE UN 3286 FLAMMABLE LIQUID, TOXIC, LIQUID, TOXIC, CORROSIVE, N.O.S. CORROSIVE, N.O.S. (CONTAINS methanol ; (CONTAINS methanol ; Tetrabutylammonium Tetrabutylammonium hydroxide), 3 (6.1+8), II, hydroxide), 3 (6.1+8), II (D/E)

UN 3286 Flammable liquid, toxic, corrosive, n.o.s. (CONTAINS methanol ; Tetrabutylammonium hydroxide), 3 (6.1+8), II

UN 3286 FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. (CONTAINS methanol ; Tetrabutylammonium hydroxide), 3 (6.1+8), II

UN 3286 FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. (CONTAINS methanol ; Tetrabutylammonium hydroxide), 3 (6.1+8), II

14.3. Transport hazard class(es) 3 (6.1, 8) 3 (6.1, 8)

3 (6.1, 8)

3 (6.1, 8)

3 (6.1, 8)

14.4. II

II

II

II

Dangerous for the environment : No

Dangerous for the environment : No

Dangerous for the environment : No

Packing group II

14.5. Environmental hazards Dangerous for the Dangerous for the environment : No environment : No Marine pollutant : No

No supplementary information available 14.6.

Special precautions for user

- Overland transport Classification code (ADR)

: FTC

Special provisions (ADR)

: 274

Limited quantities (ADR)

: 1l

Excepted quantities (ADR)

: E2

Packing instructions (ADR)

: P001, IBC02

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Mixed packing provisions (ADR)

: MP19

Portable tank and bulk container instructions (ADR)

: T11

Portable tank and bulk container special provisions (ADR)

: TP2, TP27

Tank code (ADR)

: L4BH

Tank special provisions (ADR)

: TU15

Vehicle for tank carriage

: FL

Transport category (ADR)

: 2

Special provisions for carriage - Loading, unloading and handling (ADR)

: CV13, CV28

Special provisions for carriage - Operation (ADR)

: S2, S22

Hazard identification number (Kemler No.)

: 368

Orange plates

:

Tunnel restriction code (ADR)

: D/E

- Transport by sea Special provisions (IMDG)

: 274

Packing instructions (IMDG)

: P001

IBC packing instructions (IMDG)

: IBC99

Tank instructions (IMDG)

: T11

Tank special provisions (IMDG)

: TP2, TP13, TP27

EmS-No. (Fire)

: F-E

EmS-No. (Spillage)

: S-C

Stowage category (IMDG)

: B

Stowage and handling (IMDG)

: SW2

Segregation (IMDG)

: SG5, SG8

Properties and observations (IMDG)

: Flammable, toxic, corrosive liquid. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes.

- Air transport PCA Excepted quantities (IATA)

: E2

PCA Limited quantities (IATA)

: Y340

PCA limited quantity max net quantity (IATA)

: 0.5L

PCA packing instructions (IATA)

: 352

PCA max net quantity (IATA)

: 1L

CAO packing instructions (IATA)

: 363

CAO max net quantity (IATA)

: 5L

ERG code (IATA)

: 3CP

- Inland waterway transport Classification code (ADN)

: FTC

Special provisions (ADN)

: 274, 802

Limited quantities (ADN)

: 1L

Excepted quantities (ADN)

: E2

Carriage permitted (ADN)

: T

Equipment required (ADN)

: PP, EP, EX, TOX, A

Ventilation (ADN)

: VE01, VE02

Number of blue cones/lights (ADN)

: 2

- Rail transport Classification code (RID)

: FTC

Special provisions (RID)

: 274

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Tetrabutylammonium hydroxide 40% in methanol Safety Data Sheet according to Regulation (EU) 2015/830 Date of issue: 12/09/2018 Doc No: SDS-972.06P/0

Limited quantities (RID)

: 1L

Excepted quantities (RID)

: E2

Packing instructions (RID)

: P001, IBC02

Mixed packing provisions (RID)

: MP19

Portable tank and bulk container instructions (RID)

: T11

Portable tank and bulk container special provisions (RID)

: TP2, TP27

Tank codes for RID tanks (RID)

: L4BH

Special provisions for RID tanks (RID)

: TU15

Transport category (RID)

: 2

Special provisions for carriage - Loading, unloading and handling (RID)

: CW13, CW28

Colis express (express parcels) (RID)

: CE7

Hazard identification number (RID)

: 368

14.7.

Transport in bulk according to Annex II of Marpol and the IBC Code

Not applicable

SECTION 15: Regulatory information 15.1.

Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1.

EU-Regulations

Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances 15.1.2.

National regulations

No additional information available.

15.2.

Chemical safety assessment

No chemical safety assessment has been carried out

SECTION 16: Other information Abbreviations and acronyms: ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways ADR European Agreement concerning the International Carriage of Dangerous Goods by Road ATE Acute Toxicity Estimate BCF Bioconcentration factor EC50 Median effective concentration IARC International Agency for Research on Cancer IATA International Air Transport Association IMDG International Maritime Dangerous Goods LC50 Median lethal concentration LD50 Median lethal dose LOAEL Lowest Observed Adverse Effect Level NOAEC No-Observed Adverse Effect Concentration NOAEL No-Observed Adverse Effect Level NOEC No-Observed Effect Concentration OECD Organisation for Economic Co-operation and Development PBT Persistent Bioaccumulative Toxic PNEC Predicted No-Effect Concentration RID Regulations concerning the International Carriage of Dangerous Goods by Rail SDS Safety Data Sheet STP Sewage treatment plant vPvB Very Persistent and Very Bioaccumulative 20/09/2018 www.isolab.de

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Data sources

: Classification according to Regulation (EC) No. 1272/2008 [CLP].

Other information

: DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only for this product. If the product is used as a component in another product, this SDS information may not be applicable.

Full text of H- and EUH-statements: Acute Tox. 3 (Dermal) Acute Tox. 3 (Inhalation) Acute Tox. 3 (Inhalation:vapour) Acute Tox. 3 (Oral) Acute Tox. 4 (Oral) Eye Dam. 1 Flam. Liq. 2 Skin Corr. 1 STOT SE 1 H225 H301 H302 H311 H314 H318 H331 H370

Acute toxicity (dermal), Category 3 Acute toxicity (inhal.), Category 3 Acute toxicity (inhalation:vapour) Category 3 Acute toxicity (oral), Category 3 Acute toxicity (oral), Category 4 Serious eye damage/eye irritation, Category 1 Flammable liquids, Category 2 Skin corrosion/irritation, Category 1 Specific target organ toxicity — single exposure, Category 1 Highly flammable liquid and vapour. Toxic if swallowed. Harmful if swallowed. Toxic in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage. Toxic if inhaled. Causes damage to organs.

SDS ISOLAB (EU) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product

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