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Page 1/7 Safety data sheet according to 1907/2006/EC, ... Wear self-contained respiratory protective device. ... Mild · pH-value:...

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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 28.05.2015

Version number 3

Revision: 28.05.2015

SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: IBS Special Cleaning Agent Quick · 1.2 Relevant identified uses of the substance or mixture and uses advised against · Application of the substance / the mixture · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: IBS Scherer GmbH Gewerbegebiet D-55599 GAU-BICKELHEIM DEUTSCHLAND www.ibs-scherer.de · Further information obtainable from: Tel.: +49 (0) 6701 / 93 83 - 0 Fax: +49 (0) 6701 / 93 83 -33 [email protected] · 1.4 Emergency telephone number: Giftnotruf Mainz Tel.: +49 (0) 6131 /19 24 0 (24 h erreichbar, Beratung in Deutsch u. Englisch)

SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS02 flame Flam. Liq. 3 H226 Flammable liquid and vapour. GHS08 health hazard Asp. Tox. 1 H304 May be fatal if swallowed and enters airways. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms

GHS02

GHS08

· Signal word Danger · Hazard-determining components of labelling: 2,2,4,6,6-Pentamethylheptan Alkane, (C12)-Iso · Hazard statements H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. · Precautionary statements P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P403+P235 Store in a well-ventilated place. Keep cool. (Contd. on page 2) GB

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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 28.05.2015

Version number 3

Revision: 28.05.2015

Trade name: IBS Special Cleaning Agent Quick (Contd. of page 1)

P501

Dispose of contents/container in accordance with local/regional/national/international regulations.

· 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable.

SECTION 3: Composition/information on ingredients · Description: Mixture of substances listed below with nonhazardous additions. · Dangerous components: CAS: 13475-82-6 2,2,4,6,6-Pentamethylheptan EINECS: 236-757-0 Flam. Liq. 3, H226; Asp. Tox. 1, H304 CAS: 93685-81-5 Alkane, (C12)-Iso EINECS: 297-629-8 Flam. Liq. 3, H226; Asp. Tox. 1, H304 · Additional information: For the wording of the listed risk phrases refer to section 16.

80.0 - 100.0% 0.0 - 20.0%

SECTION 4: First aid measures · 4.1 Description of first aid measures · General information: Immediately remove any clothing soiled by the product. · After inhalation: Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist. In case of unconsciousness place patient stably in side position for transportation. · After skin contact: Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. · After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: Do not induce vomiting; call for medical help immediately. Call a doctor immediately. Rinse out mouth and then drink plenty of water.

SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · For safety reasons unsuitable extinguishing agents: Water with full jet · 5.2 Special hazards arising from the substance or mixture Can form explosive gas-air mixtures. Carbon dioxide (C02) and Carbon monoxide (CO) · 5.3 Advice for firefighters · Protective equipment: Wear self-contained respiratory protective device. · Additional information Cool endangered receptacles with water spray. Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.

SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation (Contd. on page 3) GB

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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 28.05.2015

Version number 3

Revision: 28.05.2015

Trade name: IBS Special Cleaning Agent Quick (Contd. of page 2)

Do not breathe vapour. Keep away from ignition sources. Avoid contact with skin and eyes. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Prevent from spreading (e.g. by damming-in or oil barriers). Suppress gases/fumes/haze with water spray. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. Do not flush with water or aqueous cleansing agents Send for recovery or disposal in suitable receptacles. Remove from the water surface (e.g. skim or suck off). Dispose of the material collected according to regulations. · 6.4 Reference to other sections See Section 13 for disposal information.

SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good interior ventilation, especially at floor level. (Fumes are heavier than air). Do not breathe vapour. Make sure that all applicable workplace limits are observed. Avoid contact with eyes. Avoid contact with skin. Open and handle receptacle with care. Avoid splashes or spray in enclosed areas. · Information about fire - and explosion protection: Keep away from heat. Fumes can combine with air to form an explosive mixture. Flammable gas-air mixtures may form in empty receptacles. Danger of explosion if fluid enters the sewage system. Keep ignition sources away - Do not smoke. Protect against electrostatic charges. Use explosion-proof apparatus / fittings and spark-proof tools. Emergency cooling must be available in case of nearby fire. Keep respiratory protective device available. Handle only outside or in explosion protected rooms. · 7.2 Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Store in a well-ventilated place. Keep cool. Store in accordance with local/regional/national/international regulations. · Information about storage in one common storage facility: Store away from oxidising agents. · Further information about storage conditions: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store receptacle in a well ventilated area. Store only outside or in explosion proof rooms. · Storage class: 3 · 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection · Additional information about design of technical facilities: No further data; see item 7. (Contd. on page 4) GB

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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 28.05.2015

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Trade name: IBS Special Cleaning Agent Quick (Contd. of page 3)

· 8.1 Control parameters · Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists valid during the making were used as basis. · 8.2 Exposure controls · Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of work. Do not inhale gases / fumes / aerosols. Avoid close or long term contact with the skin. Avoid contact with the eyes. Do not eat, drink, smoke or sniff while working. Do not carry product impregnated cleaning cloths in trouser pockets. Apply solvent resistant skin cream before starting work. · Respiratory protection: Use suitable respiratory protective device only when aerosol or mist is formed. · Protection of hands: Protective gloves Solvent resistant gloves Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Check the permeability prior to each anewed use of the glove. To avoid skin problems reduce the wearing of gloves to the required minimum. · Material of gloves Nitrile rubber, NBR Recommended thickness of the material: ≥ ≥0.3 mm The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material For the mixture of chemicals mentioned below the penetration time has to be at least 480 minutes (Permeation according to EN 374 Part 3: Level ≥ 6). The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Tightly sealed goggles · Body protection: Protective work clothing

SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Fluid Form: Colourless Colour: (Contd. on page 5) GB

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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 28.05.2015

Version number 3

Revision: 28.05.2015

Trade name: IBS Special Cleaning Agent Quick (Contd. of page 4)

· Odour:

Mild

· pH-value:

Not applicable.

· Change in condition Melting point/Melting range: -81 °C Boiling point/Boiling range: 176-192 °C · Flash point:

45 °C

· Flammability (solid, gaseous): Flammable. · Ignition temperature:

410 °C

· Self-igniting:

Product is not selfigniting.

· Danger of explosion:

Product is not explosive. However, formation of explosive air/vapour mixtures are possible.

· Explosion limits: Lower: Upper:

0.5 Vol % 4.0 Vol %

· Density at 20 °C:

0.74 g/cm³

· Solubility in / Miscibility with Not miscible or difficult to mix. water: No further relevant information available. · 9.2 Other information

SECTION 10: Stability and reactivity · 10.1 Reactivity · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: Avoid impact, friction, heat, sparks, electrostatic charges. · 10.3 Possibility of hazardous reactions Can form explosive mixtures in air if heated above flash point and/or when sprayed or atomised. Used empty containers may contain product gases which form explosive mixtures with air. · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: Carbon dioxide (C02) and Carbon monoxid (CO) Hydrocarbons

SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity · Primary irritant effect: · Skin corrosion/irritation No irritant effect. · Serious eye damage/irritation Irritating effect. · Respiratory or skin sensitisation No sensitising effects known. · Additional toxicological information: The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version: Harmful GB

(Contd. on page 6)

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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 28.05.2015

Version number 3

Revision: 28.05.2015

Trade name: IBS Special Cleaning Agent Quick (Contd. of page 5)

SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: No further relevant information available. · 12.2 Persistence and degradability Heavily biodegradable · Other information: The product is difficultly biodegradable. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Disposal must be made according to official regulations. Must not be disposed together with household garbage. Do not allow product to reach sewage system. · Uncleaned packaging: · Recommendation: Empty contaminated packagings thoroughly. They may be recycled after thorough and proper cleaning. Packagings that may not be cleansed are to be disposed of in the same manner as the product.

SECTION 14: Transport information · 14.1 UN-Number · ADR, IMDG, IATA

2286

· 14.2 UN proper shipping name · ADR · IMDG, IATA

2286 PENTAMETHYLHEPTANE PENTAMETHYLHEPTANE

· 14.3 Transport hazard class(es) · ADR

· Class · Label

3 (F1) Flammable liquids. 3

· IMDG, IATA

· Class · Label

3 Flammable liquids. 3

· 14.4 Packing group · ADR, IMDG, IATA

III (Contd. on page 7) GB

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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 28.05.2015

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Revision: 28.05.2015

Trade name: IBS Special Cleaning Agent Quick (Contd. of page 6)

· 14.5 Environmental hazards: · Marine pollutant:

No

· 14.6 Special precautions for user · Danger code (Kemler): · EMS Number:

Warning: Flammable liquids. 30 F-E,S-D

· 14.7 Transport in bulk according to Annex II of Not applicable. MARPOL73/78 and the IBC Code · Transport/Additional information: · ADR · Limited quantities (LQ) · Transport category · Tunnel restriction code

LQ7 3 D/E

· UN "Model Regulation":

UN2286, PENTAMETHYLHEPTANE, 3, III

SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · National regulations: · Information about limitation of use: Employment restrictions concerning juveniles must be observed. Employment restrictions concerning pregnant and lactating women must be observed. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. · Department issuing MSDS: laboratory · Abbreviations and acronyms: RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) ICAO: International Civil Aviation Organisation ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) Flam. Liq. 3: Flammable liquids, Hazard Category 3 Asp. Tox. 1: Aspiration hazard, Hazard Category 1 GB