ChemicalReactions Organic and Inorganic Systems

vi tableofcontents selectivity induced by heterogeneous conditions in the alkylation of anionic reagent / g. bram 191 the reactions in clays and pilla...

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Chemical Reactions in

Organic and Inorganic Constrained Systems edited by

R. Setton Research

on

Imperfectly Crystallized

Solids,

National Centre for Scientific Research, Orleans, France

UNIVERSITATSBIBLIOTHEK HANNOVER

TECHNISCHE

INFORMATIONSBIBLIOTHEK

D. Reidel

Publishing Company

Dordrecht / Boston / Lancaster / Tokyo Published in cooperation with NATO Scientific Affairs Division

A/ o? a

TABLE

/

V

*>

5*

/

«"

OF CONTENTS

List of Participants PREFACE

/

REACTIONS

CHIRAL,

J.

J.

vii

Fripiat

and

IN CONSTRAINED

SIZE AND

P,

Sinay

SYSTEMS

/

TO MIMIC ENZYMES

Wamheim

1

/ K. Fujita

11

REPORT FROM THE BATTLE FRONT /

-

IN MIXED

17 CHELATE

AND MACROCYCLIC

THEIR CHARACTERISTIC and

C.

/

STRUCTURAL FEATURES

J.

Gutsche

Lefebvre,

29

Thomas

M.

Williams

49

STRUCTURAL AND CATALYTIC

SHAPE

/CD.

SYSTEMS

RHODIUM AND IRIDIUM CARBONYL COMPLEXES ENTRAPPED IN F.

xv

Breslow

R.

ZEOLITES:

T.

Tabushi

I.

6A6X-DISULFONATES OF CYCLODEXTRINS

WEAK FORCES

/

SUMMARY

SHAPE RECOGNITION OF GUESTS BY MODIFIED

CYCLODEXTRIN

ATTEMPTS

xiii

A

-

Gelin,

P.

PROPERTIES

/

C.

ZEOLITES.

Naccache,

Ben Taarit

and Y.

81

SELECTIVE ALKYLATION REACTIONS OVER MEDIUM-PORE HIGH SILICA ZEOLITES

and J. ZEOLITE-INDUCED

/ A.

I.

S.

Barri,

Cartlidge, 87

SELECTIVITY

ALIPHATIC M.

A.

Ashton, S.

G.

Dwyer IN

THE

CONVERSION

/

CARBOXYLIC ACIDS L.

Wydoodt,

Jacobs,

J.

M.

A.

THE LOWER

OF

Vervecken, Y.

Martens,

and

P.

Servotte, A.

95

Jacobs

SELECTIVITY INDUCED BY THE VOID STRUCTURE OF ZEOLITE-BETA AND FERRIERITE IN THE HYDROCONVERSION REACTION OF N-DECANE J. COKE

A.

Perez-Pariente, and

Martens, J.

FORMATION ON PROTONIC •ZEOLITES: M.

Guisnet,

P.

Magnoux,

P.

A.

Jacobs

/ 115

RATE AND SELECTIVITY /

and

C.

Canaff

131

ACID-CATALYZED REACTIONS FOR THE CHARACTERIZATION OF THE POROUS STRUCTURE OF ZEOLITES / F. G.

Perot, and M.

SYNTHESIS AND

PILLARED

CLAYS:

PILLARED

MONTMORILLONITE AND

PROPERTIES

/

G.

Ribeiro,

R.

F.

Lemos, 141

Guisnet

STRUCTURAL FEATURES BEIDELLITE.

Poncelet

and

A.

/

T.

J.

Pinnavaia 151

ACIDITY AND CATALYTIC 165

Schutz

INTRACRYSTALLINE COMPLEXATION BY CROWN ETHERS AND CRYPTANDS IN CLAY MINERALS

/ E.

Ruiz-Hitzky

and B.

Casal

179

vi

TABLE OF CONTENTS

SELECTIVITY

INDUCED BY HETEROGENEOUS

OF ANIONIC THE REACTIONS PREPARATIVE

/ G.

CONDITIONS

IN

THE

ALKYLATION 191

Bram

Ballantine

PILLARED CLAYS

/

J.

A.

CHEMISTRY USING CLAYS

/

A.

Cornells

CLAYS

ORGANIC

P. CLAY

IN

REAGENT AND

197

and

Laszlo

CATALYZED J.

213 OF

ENE-REACTIONS; SYNTHESIS

F.

y-LACTONES /

Roudier and A. Foucaud

229

PHOTOINDUCED CHARGE SEPARATION AT INORGANIC AND ORGANIC

INTERFACES

/

D.-Y.

Chu, R. Stramel, S. Hashimoto, T. Nakamura, Murtagh, J. Kuczynski, B, Milosavljevic, J. Wheeler,

J.

and J. A

COMPARISON

OF

Thomas

K.

237

-

THE FORWARD AND BACK PHOTOELECTRON

DIRECT AND and B.

/

REVERSE MICELLES

M.

P.

TRANSFERS

Pileni,

P.

Lerebours Pigeonniere

253

EFFECT OF MICROEMULSIONS ON PHOTOCHEMICAL REACTIONS / M. ENERGETICAL

AND

Riviere

CONSTRAINTS ON ADSORPTION AND REACTION ON CLAY SURFACES / H. van Damme, P. Levitz, and

Gatineau

283

REACTIONS BETWEEN ACIDIC MICROEMULSIONS AND CALCIUM CARBONATE / J. Sjoblom, H. Soderlund, and T. Warnheim PHOTOCHEMICAL

REACTIONS AT

WITH THE GEOMETRICAL AND

CRYSTALLINE

/

R.

H.

/

CONSTRAINTS

D.

IN REDOX

Orrit

315

INTERCALATION 323

PROPERTIES AND REACTIVITY

/

G.

305

INVESTIGATED

Mobius and M.

Schollhorn

BRONZES:

SILICIC ACIDS

H.

THE AIR-WATER INTERFACE

REFLECTION METHOD

ELECTRONIC

SYSTEMS TRANSITION METAL

263

GEOMETRICAL

KINETICS

L.

IN

Brochette,

Lagaly,

H.-M.

/

Riekert,

P.

A.

Sermon

341

and

Kruse

361

THE BEHAVIOUR OF SOME ALKALI METAL GRAPHITE COMPOUNDS TOWARDS SUNDRY REAGENTS

/ R.

Setton

and C.

Mazieres

381

MECHANISM OF THE CATALYTIC

GASIFICATION AND REACTIVITY OF GRAPHITE / H. Heinemann and G. A. Somorjai

REACTIVITY OF HYDROCARBONS ON CONTACT WITH THE FIRST

STAGE

SUPERACID:

ANTIMONY PENTAFLUORIDE INTERCALATED

GRAPHITE / J. AN EXAMPLE

SOLID

Sommer

411

OF CRYSTALLINE GROWTH IN A CONSTRAINED MEDIUM: INTERCALATION P.

401

OF METALS AND

Lagrange and

A.

THE

METALLIC ALLOYS INTO GRAPHITE /

Herold

421

ORDER-DISORDER PHENOMENA IN GRAPHITE INTERCALATION COMPOUNDS AND REDUCTION REACTIONS IN ALKALI METAL-INTERCALATED COMPOUNDS

INDEX

OF

GRAPHITE

R.

Schlogl

/

H.

P.

Boehm,

Ko Y.-Sh.,

B.

Ruisinger,

and

429 441